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Tuning methanol-CO selectivity in CO 2 hydrogenation by Ga coordination engineering in ZnGa 2 O 4

Nature · By Zhufu Fu ·

The Brief

  • A study in Nature Communications, published online 14 November 2026, reports on CO2 hydrogenation over ZnGa2O4.
  • The authors show that tuning gallium coordination in ZnGa2O4 directs the reaction toward distinct products, methanol or carbon monoxide.
  • The abstract describes controlling whether CO2 hydrogenation yields methanol or CO as a long-standing challenge.

Why it matters

Selectively producing methanol rather than CO from CO2 is a key requirement for converting captured carbon dioxide into useful fuels and chemicals, and this work suggests catalyst structure at the gallium site is a practical lever for controlling that selectivity.

Who’s affected

  • catalysis researchers
  • chemists working on CO2 utilisation
  • #co2 hydrogenation
  • #methanol
  • #carbon monoxide
  • #catalysis
  • #selectivity
  • #zinc gallate

Nature Communications, Published online: 14 November 2026; doi:10.1038/s41467-026-79788-9 Controlling whether carbon dioxide hydrogenation yields methanol or carbon monoxide remains challenging. This study shows that tuning gallium coordination in ZnGa₂O₄ directs distinct…

Timeline

  1. Published online in Nature Communications (doi:10.1038/s41467-026-79788-9)

  2. nature.com

    Tuning methanol-CO selectivity in CO 2 hydrogenation by Ga coordination engineering in ZnGa 2 O 4

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    Tuning methanol-CO selectivity in CO 2 hydrogenation by Ga coordination engineering in ZnGa 2 O 4 – The Morning Science