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Thermodynamic-guided tailoring of single-atom coordination environments via oxygen chemical potential for efficient C-N coupling

Nature · By Qingna Gong ·

The Brief

  • Precise control of single-atom coordination is hindered by thermodynamic and kinetic constraints.
  • The authors report tuning Fe-O coordination on CoWO4 by adjusting oxygen chemical potential.
  • The work targets more efficient C-N coupling.

Why it matters

It offers a thermodynamic guide for controlling the local coordination environment of single-atom catalysts, which can make such catalysts more predictable to design.

Who’s affected

  • catalysis researchers
  • materials chemists working on single-atom catalysts
  • #single-atom catalysis
  • #c-n coupling
  • #coordination chemistry
  • #thermodynamics
  • #cowo4

Nature Communications, Published online: 13 November 2026; doi:10.1038/s41467-026-79091-7 Precise control of single-atom coordination is hindered by thermodynamic and kinetic constraints. Here, the authors report tuning Fe-O coordination on CoWO4 via oxygen chemical potential…

Timeline

  1. Published online in Nature Communications (doi:10.1038/s41467-026-79091-7)

  2. nature.com

    Thermodynamic-guided tailoring of single-atom coordination environments via oxygen chemical potential for efficient C-N coupling

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    Thermodynamic-guided tailoring of single-atom coordination environments via oxygen chemical potential for efficient C-N coupling – The Morning Science