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Photocatalytic radical hydrogenation of unactivated alkenes via an intermolecular hydrogen-atom-transfer relay

Nature · By Weiqiao Lan ·

The Brief

  • A research article titled 'Photocatalytic radical hydrogenation of unactivated alkenes via an intermolecular hydrogen-atom-transfer relay' was published online in Nature Communications on 14 November 2026 (doi:10.1038/s41467-026-79704-1).
  • The article's abstract excerpt notes that cross-electrophile coupling between unactivated alkyl halides and alkynyl halides has long been challenged by reactivity mismatch and poor chemoselectivity.
  • The excerpt is truncated before the authors' results, so the specific findings are not available from the provided sources.

Why it matters

The work addresses hydrogenation of unactivated alkenes using a photocatalytic hydrogen-atom-transfer relay, a route relevant to synthetic chemists working on radical methods. The available excerpt does not give the full results, so its practical reach cannot yet be judged.

Who’s affected

  • synthetic organic chemists
  • researchers in photocatalysis and radical chemistry

Nature Communications, Published online: 14 November 2026; doi:10.1038/s41467-026-79704-1 Cross-electrophile coupling between unactivated alkyl halides and alkynyl halides has long been challenged by reactivity mismatch and poor chemoselectivity. Here the authors report…

Timeline

  1. Published online in Nature Communications

  2. nature.com

    Photocatalytic radical hydrogenation of unactivated alkenes via an intermolecular hydrogen-atom-transfer relay

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    Photocatalytic radical hydrogenation of unactivated alkenes via an intermolecular hydrogen-atom-transfer relay – The Morning Science