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Phosphorus-mediated reverse hydrogen spillover enables rate-matched nitrate-sulfate paired electrolysis for ammonium persulfate synthesis

Nature · By Yaobin Wang ·

The Brief

  • Researchers report a phosphorus-mediated reverse hydrogen spillover mechanism for electrolysis.
  • The mechanism is described as enabling rate-matched paired nitrate-sulfate electrolysis for ammonium persulfate synthesis.
  • The work targets electrochemical conversion of nitrate-rich wastewater into valuable ammonium salts.

Why it matters

It describes a possible electrochemical route to turn nitrate-rich wastewater into ammonium salts, which matters to researchers working on wastewater treatment and electrosynthesis.

Who’s affected

  • electrochemistry researchers
  • wastewater treatment researchers
  • #electrochemistry
  • #nitrate reduction
  • #hydrogen spillover
  • #wastewater treatment
  • #ammonium persulfate

Nature Communications, Published online: 15 November 2026; doi:10.1038/s41467-026-79620-4 Electrochemical conversion of nitrate-rich wastewater to valuable ammonium salts is promising. We report a phosphorus-mediated reverse hydrogen spillover mechanism that synchronizes…

Timeline

  1. Published online in Nature Communications (doi:10.1038/s41467-026-79620-4)

  2. nature.com

    Phosphorus-mediated reverse hydrogen spillover enables rate-matched nitrate-sulfate paired electrolysis for ammonium persulfate synthesis

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    Phosphorus-mediated reverse hydrogen spillover enables rate-matched nitrate-sulfate paired electrolysis for ammonium persulfate synthesis – The Morning Science