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High-pressure synthesis of a polymeric N 3 H 2 solid stabilized by hydrogen bonds

Nature · By Umbertoluca Ranieri ·

The Brief

  • Laser-heating nitrogen–hydrogen mixtures at about 139 GPa produces N3H2, a crystalline polymeric solid.
  • The N3H2 solid contains only single N–N bonds.
  • The material is reported to have a high energy density.

Why it matters

It shows that a nitrogen-rich polymeric solid can be made and held together by hydrogen bonds at high pressure, which is relevant to research on high-energy-density materials.

Who’s affected

  • high-pressure chemists and physicists
  • materials scientists studying energetic nitrogen compounds
  • #high pressure
  • #nitrogen hydrogen
  • #polymeric solid
  • #energy density
  • #hydrogen bonding

Nature Communications, Published online: 11 November 2026; doi:10.1038/s41467-026-79382-z Laser-heating nitrogen–hydrogen mixtures at about 139 GPa produces N3H2, a crystalline polymeric solid with only single N–N bonds. The new material has a high energy density, with a…

Timeline

  1. Published online in Nature Communications

  2. nature.com

    High-pressure synthesis of a polymeric N 3 H 2 solid stabilized by hydrogen bonds

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