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Anion manipulation for breaking through 3.0 V of aluminium–graphite batteries

Nature · By Ke Guo ·

The Brief

  • Aluminium–graphite batteries are limited by electrolyte decomposition above 2.5 V, according to the paper's abstract.
  • The authors regulate chloroaluminate anions using a fluorine-rich, framework-confined quasi-solid-state approach.
  • The study, published in Nature Communications, reports aluminium–graphite batteries operating past 3.0 V.

Why it matters

Aluminium–graphite batteries are a potential low-cost, abundant-material alternative for energy storage, and the voltage ceiling set by electrolyte breakdown is a key obstacle to their practical use.

Who’s affected

  • battery and electrochemistry researchers
  • researchers and engineers interested in aluminium-based energy storage
  • #aluminium-graphite batteries
  • #electrolyte decomposition
  • #chloroaluminate anions
  • #quasi-solid-state electrolyte
  • #energy storage

Nature Communications, Published online: 13 November 2026; doi:10.1038/s41467-026-79156-7 Aluminium–graphite batteries are limited by electrolyte decomposition above 2.5 V. Here, authors regulate chloroaluminate anions with a fluorine-rich, framework-confined quasi-solid-state…

Timeline

  1. Published online in Nature Communications

  2. nature.com

    Anion manipulation for breaking through 3.0 V of aluminium–graphite batteries

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    Anion manipulation for breaking through 3.0 V of aluminium–graphite batteries – The Morning Science