# Photoenzymatic control of phosphorus radicals

Source: [nature.com](https://www.nature.com/articles/s41929-026-01633-5) · 2026-11-13 · Physics
Page: https://themorning.science/story/photoenzymatic-control-of-phosphorus-radicals-d2f6710b1fc02a1e
Kind: research · Impact: medium

## In brief

- Published online in Nature Catalysis on 13 November 2026 (doi:10.1038/s41929-026-01633-5).
- Photoenzymatic catalysis has enabled an increasingly diverse range of asymmetric radical transformations.
- Phosphorus-centred radicals had previously remained beyond the reach of photoenzymatic catalysis; the article reports that engineered enzymes now enable control of them.

## Why it matters

It extends photoenzymatic asymmetric radical chemistry to phosphorus-centred radicals, a class previously considered out of reach, which may matter for chemists building chiral phosphorus-containing molecules.

## Timeline

- 2026-11-13: Published online in Nature Catalysis

## Coverage

- [Photoenzymatic control of phosphorus radicals](https://www.nature.com/articles/s41929-026-01633-5) — nature.com, 2026-11-13

Tags: photoenzymatic catalysis, radical chemistry, biocatalysis, organophosphorus, asymmetric synthesis

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Brief generated by AI (claude-haiku-5-5) from the reporting listed under Coverage. Headlines belong to their publishers. The Morning Science – https://themorning.science